Need to learn about Scanning with Autoxray 5000

Hello everyone ! I am trying to learn about scanning because the Autoxray 5000 i bought has more in it than i know how to use. I had an Actron scanner for a year and only used it for checking codes. Now i have a 94 Camaro with obd1 pcm so now i want to learn everything i can. I am not a mechanic but seem to fix everyones car around. Any Suggestions ?
Is it possible to use a pc based software with the Autoxray to trouble shoot problems ?